Who is Henwil? -- Our region deserves better reporting.

10,000 gallons of an industrial detergent overflowed into the Mon river. The cleanup is mishandled and the toxic pollutant dumped again, this time into the Allegheny.  

Both our local papers cover the story half-wittedly, leaving readers to piece together what happened and track down the who's and why's.

Industrial detergent spilled in Mon, Allegheny rivers
Saturday, September 03, 2011

State environmental officials say the same kind of industrial detergent that spilled into the Monongahela River in Fayette County a few days ago has now gone into the Allegheny River from a Harmar treatment plant.

The spill of ethoxylated alcohol from the Allegheny Valley Joint Sewage Authority treatment plant in Harmar occurred Thursday, said plant manager Rich Chiavetta. The state Department of Environmental Protection says it was reported Friday. Mr. Chiavetta said about 10,000 gallons was released. The Pittsburgh Water and Sewer Authority said the drinking water supply was not affected.

On Wednesday, the same chemical leaked from a containment pit in Newell into the Monongahela River. A number of fish were killed due to the spill.

The chemical is found in some household detergents and can be harmful in concentrated form, but officials say it is toxic to aquatic organisms.

First published on September 3, 2011 at 2:08 pm

http://www.post-gazette.com/pg/11246/1172067-100.stm?cmpid=latest.xml

The trib-review does a bit better if you read it three times and try to put the puzzle together...

Industrial detergent, toxic to fish, spills into Allegheny River

The same industrial detergent that spilled into the Monongahela River this week in Fayette County flowed into the Allegheny River from the Allegheny Valley Joint Sewage Authority treatment plant in Harmar Friday, the state Department of Environmental Protection said.

The product -- ethoxylated alcohol, also known as Trideceth-3 -- is also found in some household detergents and can cause skin and eye irritation in humans. But it is toxic to aquatic organisms, according to a hazardous materials data sheet. Allegheny County emergency dispatchers said the spill was reported Friday afternoon near the Hulton Bridge and that the Pittsburgh Water and Sewer Authority immediately closed its intake valve in Aspinwall to prevent the contaminant from entering the water system.

However, Rich Chiavetta, plant manager of the Allegheny Valley Joint Sewage Authority, said the contaminant actually was released into the Allegheny River on Thursday.

The concentrated detergent spilled into the Monongahela River on Wednesday afternoon from the Henwil Corp. in Newell, a company that blends chemicals for water treatment plants*.  A company spokesman said 2,620 gallons of ethoxylate detergent spilled and filled a containment pit, but some leaked through a crack in the wall of the pit. Several dozen fish were killed by the spill.

DEP spokeswoman Katy Gresh said McCutcheon Enterprises Inc., a waste management company in Allegheny Township, Westmoreland County, cleaned the spill. Gresh said she understands McCutcheon took the detergent that it cleared from the Mon, transported it to Harmar, and deposited it at the treatment plant for disposal. Chiavetta, who believes about 10,000 gallons of the contaminant was released into the Allegheny, said proper procedures were followed. He said that the plant accepted the same industrial detergent several weeks ago, analyzed it and treated it without incident. Chiavetta suspects the detergent this time was more "highly concentrated ... and it upset the plant."

Gresh said the DEP is investigating.

The Pennsylvania Fish and Boat Commission said preliminary indications are that fewer than 100 fish have been killed but there could be more.

The Pittsburgh Water and Sewer Authority said it was notified at 1:30 p.m. Friday about the fouled water and took immediate steps to make sure the drinking supply remained safe. "None of this substance passed into Pittsburgh's drinking water supply," a company statement said.

Source:  http://www.pittsburghlive.com/x/pittsburghtrib/news/pittsburgh/s_754930.html

So my read ...

It seems the waste managment company, McCutcheon Enterprises, responsible for cleaning up the spill that leaked into the Mon from Henwil's containment pit, took the "spilled Trideceth-3, an ethoxylated alcohol" to a wastewater treatment facility on the Allegheny (who had accepted and treated this chemical before), but this load was more concentrated and "upset the plant." leading to a second release of the industrial detergent into the Allegheny river.  Hmnn a little more info here -- what are the water treatment procedures for this chemical prior to releasing it into waterways? Is it dilution or some other treatment process? What does "upset" mean?  What caused the alarm bells to ring and alert the PSWA to shut down the drinking water intake?

*Also they mischaracterize the company behind the source of the spill -- to call Henwil Corp a company that blends chemicals for water treatment plants is a partial description at best. These folks provide and blend water treament chemicals for industrial uses -- including slickwater hydraulic fracturing and treating of produced waters from natural gas drilling. 

Note, Henwil on their website claims ...

"We are located about 50 miles south of Pittsburgh, Pennsylvania on the Monongahela River. Our manufacturing facility offers interstate, rail, and barge access. The plant boasts tankage from 500 gallons to 3.5 million gallons. Blending tanks range from 50 gallons to 10,000 gallons. Reactor sizes are 50 to 4,000 gallons.

At Henwil, our goal is to help you manage your water treatment needs. Whether it is water produced during oil and gas well drilling, mineral slurry drying, or incoming water clarification at a paper mill, we have the experience and knowledge to benefit your process."

NB: ethoxylated alcohol is an additive, or friction reducer used in slickwater hydraulic fracturing, in other words natural gas drilling. 

See: SPE 119900 Critical Evaluations of Additives Used in Shale Slickwater Fracs

Let's hope the DEP's investigation brings some clarity to the situation, as well as processes to avoid this ineptitude in the future.

 

Aerial view of the Henwil chemical mixing and storage facilities on the Monongehela in Newall, PA.
Source: Henwil

An industrial detergent spilled a second time and flowed into the Allegheny River from the Allegheny Valley Sewage Treatment plant according to the state DEP.
Source: WPXI

10 responses
"Let's hope the DEP's investigation brings some clarity to the situation, as well as processes to avoid this ineptitude in the future." Those processes ought to involve an enforcement action including a fine and probationary period, as allowed and required by law. Let's see what the amount of the fine is, given our current DEP's waxing and waning and dubious record regarding proactive regulatory action regarding Marcellus shale and other environmental protection issues in Pa lately. The waste generator providing wastewater to a treatment plant is obligated to disclose the contents and concentrations of its wastewater to the treatment plant, via representative sample testing and other means. The concentration claimed by the generator sure sounds like it was quite different than the true concentration unless there is more information to the story. Negligent sampling strategy and mis-characterizing wastewater is a serious violation with a serious fine, unless you're let off the hook by a casual environmental regulatory agency.
Here's a link to Allegheny Valley Joint Sewage Authority NPDES permits thru 2010. www.epa.gov/npdescan/PA0026255FP.pdf

Anyone know how to read this and understand there permitting license per the spilled chemical?

And the EPA Inspection / Compliance Record -
Note a 2011 TDS violation
http://www.epa-echo.gov/cgi-bin/get1cReport.cgi?tool=echo&IDNumber=110000559529
PaDEP almost certainly will issue a fine  but it remains to be seen if it will be a slap on the wrist or a serious fine.  It would be helpful to review the PaDEP file for the two releases, particularly the first release and cleanup.  A member of the public may review DEP public files for these two treatment plant releases.  Call the PaDEP southwest regional office in Pittsburgh on Washingtons Landing and tell them you want to request review of these files.  They may well ask you to fill out a one page public file review request form, it is easy to fill out.  You need to identify the two releases.  They then tell you the earliest date and time to review the file. Then go in and copy the file on their copier and post it online or email it to me, or if you elect to go, tell me when the file review is and I'll go and review it with you.  You can then read the Dep on scene report regarding these spills.  It will likely state the violation. It is free to review a file.  There is a nominal copying charge.  
 
Ken
The TDS violation could be due to frac water discharged to the treatment plan if they accepted it, but it could be due to other sources as well. 

Thanks Ken for your research suggestions here. Will try to make sure this story continues to be covered in the press.
The Governor announced this week he is replacing the PaDEP Southwest Regional Director (in Pittsburgh) with a new appointment.  I don't know who, perhaps someone from industry based on Corbett's track record, whereas Rendell promoted from within the PaDEP.  It will be interesting to see the credentials of the new director (I hope the PPG and other media do a lengthy article on the new Director's background) and whether they issue a stiff penalty or slap on the wrist for the previously discussed release/discharge of chemicals to the River.  Btw, I think "spill" is the wrong word to use for what happened.  It makes it sound like an accident no one could have predicted. 
 
The MDS Sheet on Trideceth-3 (ethoxylated alcohol)
EXCERPTED www.sasoltechdata.com/MSDS/NVTDA-3.pdf

Note precautions for spills.

"ACCIDENTAL RELEASE MEASURES

Evacuate personnel to safe areas. Remove all sources of ignition. Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national
regulations (see section 13). Do not flush into surface water or sanitary sewer system."

-and-

"Waste Code

Any unused product or empty containers may be disposed of as non-hazardous in accordance with state and federal requirements. Re-evaluation of the product may be required by the user at the time of disposal, since the product uses, transformations,mixtures, contamination, and spillage may change the classification. If the resulting material is determined to be hazardous, please dispose in accordance with state and federal (40 CFR 262) hazardous waste regulations."

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